47, 96519653. 6fh, S7 and S8). volume10, Articlenumber:8757 (2020) Adv. SWV of Ni foil after adding the Fe salt and CV (red). (HR)TEM images of the mechanically separated solid of the operated Ni foam at 10.0V with different magnifications. The cycling stability was studied by using the LANHE battery testing system (CT2001A). Another study confirmed that OER could proceed on Ni(IV) sites16,17. 29:1809004. doi: 10.1002/adfm.201809004, Huang, P., Lethien, C., Pinaud, S., Brousse, K., Laloo, R., Turq, V., et al. Power densities and energy densities of the AFSC devices in comparison with the state-of-the-art reported supercapacitors based on Ni(OH)2 materials. Oxygen-evolution reaction by nickel/nickel oxide interface in the presence of ferrate(VI). (C) Bending angle-tests of the AFSC, inset is the digital photograph. Ye, J.-M., He, D.-H., Li, F., Li, Y.-L. & He, J.-B. 136, 67446753, https://doi.org/10.1021/ja502379c (2014). However, it transforms to -Ni(OH)2 in alkaline solutions, leading to many investigations into the possibility of stabilized -Ni(OH)2 electrodes for industrial applications. This could show that Fe ions on the surface of Ni oxide were directly involved in OER or were important to the activation of Nioxide toward OERs. On the other hand, it seems that these charges are used by Fe to increase OER (B area). After the deaeration of a KOH solution (1.0mM), Ni2O3 was added, but no clear oxygen evolution was observed (Fig. Inset of C is a high-magnification SEM image. (F) Capacitance retention after 5,000 cycling times. Impressively, at a power density of 1.5 kW kg1, the AFSC can keep a high energy density of 62 Wh kg1. Graphite electrode has no synergistic interaction with the Fe salt and the subtraction of the CV for graphite (green plot) in the absence and presence of Fe shows the effect of Fe on the electrode toward OER (Fig. Corros Sci. Subsequently, the clean Ni foam was added into a Teflon liner together with the precursor solution. Therefore, the oxidation states of Ni and Fe, and the mechanism of OER by Fe-Ni oxide are challenging issues in the field. If we subtract the pure effect of Fe (green plot) from the orange plot in Fig. Read more about how to correctly acknowledge RSC content. performed the experiments. Mater. The HRTEM images also indicated a crystal lattice spacing of 0.210.23nm, corresponding to the (101) plane of Ni(II) hydroxide (ref. SEM images of the foam as an anode electrode (amperometry at 1.46V in KOH (pH13)), after adding the Fe salt, showed nanoparticles on the surface of the electrode (ca. Because soluble nickel compounds may affect the electrochemistry of the electrode24, no nickel oxide was used to purify12 the electrolyte in our experiments. [FeO4]2, a tetrahedral ion with violet color, has a strong oxidizing activity and is relatively stable at high pH. Uncovering the role of oxygen in Ni-Fe(OxHy) electrocatalysts using in situ soft x-ray absorption spectroscopy during the oxygen evolution reaction. Z. Anorg. The CV curves of Ni(OH)2 nanoplates are obtained at different scan rates ranging in potential window from 0 to 0.7 V (Figure 3B). Revised Pourbaix diagrams for nickel at 25300 C. After that, the Teflon liner was sealed by a reaction kettle and heated in an oven. Beta-phased Ni(OH)2 nanowall film with reversible capacitance higher than theoretical faradic capacitance. (2007). Mater. Multicomponent hierarchical Cu-doped NiCo-LDH/CuO double arrays for ultralong-life hybrid fiber supercapacitor. J. 2.6 Ionic and Molecular Compounds - Chemistry 2e | OpenStax V+ (V) and V (V) are the potential window of positive and negative electrode, respectively. . First, a Ni foam was placed under oxidation conditions at 10.0V for 20minutes in a two-electrode setup in a KOH solution (pH13). Trapping an iron (VI) water-splitting intermediate in nonaqueous media. Formation of an insoluble compound will sometimes occur when a solution containing a particular cation (a positively charged ion) is mixed with another solution containing a particular anion (a negatively charged ion). (E) XPS peaks of Ni 2p. Scientific Reports (Sci Rep) A Ni foam was operated at 10.0V, and then the Ni oxide/Ni interface was used for the electrochemical investigation. Toxicity and related safety concerns have driven research into increasing the energy density of Ni(OH)2 electrodes, such as the addition of calcium or cobalt hydroxides. Nanoscale, https://doi.org/10.1039/C9NR09460A (2020). Wiechen, M., Najafpour, M., Allakhverdiev, S. I. At the end of the exchange process, the resin beads have loaded all cations and . Soc. S10) (Ref. Figure 2. The structure, morphology, and composition of the samples were studied by using an X-ray diffractometer (XRD, D8 Advance, Bruker), a field-emission scanning electron microscope (FESEM; JEOL JSM7100F), and an atomic force microscope (AFM, Dimension FastScan, Bruker). 6 Li ( s) + N 2 ( g ) 2 Li 3 N ( s) Click here to check your answer to Practice Problem 1 The Role of Oxidation Numbers in Oxidation-Reduction Reactions This may take some time to load. Lithium iodide: positive ion: Li^+ Negative ion: I^- Formula: LiI Aluminum Oxide positive ion: Al^3+ negative ion: O^2- Formula: Al2O3 Know the formula, positive, and negative ions of ionic compounds. After adding the Fe salt at this range (Fig. Jin, Alp, and Stah detected Fe(IV) by the operando Mssbauer spectroscopic studies of a 3:1 Ni:Fe layered hydroxide20. In Nioh 1 the focus is more on humanoid I feel while Nioh 2 focusey more on yokai. Introduction The research and the design of hydrogen negative ion sources have been extensively performed in connection with neutral beam injection heating [[1], [2], [3]] and ion guns for proton accelerators [ [4], [5], [6], [7]]. PDF Nickel Metal Hydride (NiMH) - Energizer 8:602322. doi: 10.3389/fchem.2020.602322. Tichenor, R. L. Nickel oxides-relation between electrochemical and foreign ion content. Wulfsberg, G. Principles of descriptive inorganic chemistry. Not oxidized by air under ordinary conditions. code: 01-076-2301; crystal system: Orthorhombic; a (): 3.8700; b (): 12.4000; c (): 3.0600; (): 90.0000; (): 90.0000; (): 90.0000; volume of cell: 586.38 3). The study of Ni 2 O 3 H synthesis conditions outlined that -NiOOH and III-NiOOH phases display instability versus electrolyte at elevated temperature, leading to the irreversible formation of Ni 2 O 3 H . The weak bonds that form between the solute and the solvent compensate for the energy needed to disrupt the structure of both the pure solute and the solvent. Before adding the Fe salt in KOH (pH13), a peak at 1.37V was observed (Fig. A. Surface interrogation scanning electrochemical microscopy of Ni1xFex OOH (0A new potassium dual-ion hybrid supercapacitor based on battery-type Ni Nickel-cadmium battery - Wikipedia Self-powered electrochemical deposition of Cu@Ni(OH)2 nanobelts for high performance pseudocapacitors. LSVs after 1st and 100th CVs for Ni foil before adding the Fe salt are shown in blue and green, respectively. Veprek, J. Siska and V. Ettel. SWV of Ni foil before adding the Fe salt (blue). Finally, the proper formula for an ionic compound always has a net zero charge, meaning the total positive charge must equal the total negative charge. Funct. The orange plot is just bigger, and its onset of OER is observed at a low overpotential. J. Soc. Thus, it is concluded thatthe separated phases such as Fe(OH)3 and FeOOH are not necessary for oxidizing water. Liu, Z., Zha, M., Wang, Q., Hu, G. & Feng, L. Overall water splitting reaction efficiently catalyzed by a novel bi-functional Ru/Ni3N-Ni electrode. Chemical formulas for ionic compounds are called ionic formulas. 8. 134, 377384, https://doi.org/10.1149/1.2100463 (1987). ADS Obviously, compared with the individual AFSC, the discharge time of two AFSC in parallel connection is much longer at the same current density, indicating that the capacity is increased by parallel connection. To determine the proper formula of any combination of ions, determine how many of each ion is needed to balance the total positive and negative charges in the compound. A 6, 1741717425. (F) The cyclability of the electrode, the capacitance retention remains 86.3% after 5,000 cycles. In the next step, OER of [FeO4]2 and Ni2O3 under chemical conditions was investigated. Chem. Adding Ni(II) ions or nickel hydroxide significantly increased OER of a K2FeO4 solution in a KOH solution (1.0mM).
Nickel-iron battery - Wikipedia Though, it was reported that after the oxidation of Ni(III) to Ni(IV), the activity toward OER would be observed30. The green arrow indicates the time of the addition of the Fe salt (e). Some experimental methods and DFT calculations of Ni-Fe oxides have shown that OER occurs at Fe-sites embedded in the Ni oxide15. After the 100th CV, the Fe salt was added to the electrolyte. Compared to soluble Ni(II) ions or Ni2O3, large amounts of oxygen evolution was detected in the presence of Fe/Ni hydroxide or Ni(II) hydroxide and K2FeO4. Structure of Ni (OH)2 - RSC Publishing Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. By mixing 2 g of KOH, 2 g of PAAK, and 20 ml of deionized water under stirring at room temperature, the PAAK/KOH gel electrolyte is ready to use when it became clear and transparent. J. Article Oxygen-evolving catalysts are usually powders placed onto conductive substrates by binders. A new approach to high-performance flexible supercapacitors: mesoporous three-dimensional Ni-electrodes. After adding the Fe salt, the peak was observed at 1.42V. The effect of different scan rates on OER, Ni oxidation and reduction peaks were also studied. PubMedGoogle Scholar. The numbers show the onsets of OER for LSVs (c). Adding large amounts of Fe salt had no significant effect on OER compared to a small amount of Fe salt. It is found naturally as a translucent emerald-green crystal formed in thin sheets near the boundaries of idocrase or chlorite crystals. 10, 40254031. (2014). Acetate anion-intercalated nickel-cobalt layered double hydroxide nanosheets supported on Ni foam for high-performance supercapacitors with excellent long-term cycling stability. Nickel-cadmium batteries [1,3,5,7,8,22] use nickel oxides as active material for the positive electrode and cadmium oxide and cadmium metal at the negative polarity. We thank Prof. S.H. The effect of the step by step addition of Fe ions to Ni oxide was studied. Energy Mater. However, Fe(IV) ions do not account for the catalytic activity20. After 5,000 cycles, the specific capacitance stills retain 86.3% of the original value, demonstrating a good cycling stability. Surprisingly, however after adding more Fe salt, OER was increased. The changes correspond to the incorporation of Fe impurity in KOH or electrochemical cell to Ni oxide. Cupric nitrate | Cu(NO3)2 | CID 18616 - PubChem 70100nm) (Figs. The mechanism of negative and positive hydrogen ions production on the
Meanwhile, the ultra-thin thickness of the nanoplates can effectively avoid the influence caused by layers stacking. However, some groups reported that Fe ions in electrolyte react with the surface of Co, Ni, Cu, Ag, Au, but not with Ti electrodes, and form the active sites for OER12,14. After adding the Fe salt at this range, a few increases (1.3 times) in OER was observed, which was constant during the time of reaction (Fig. ACS Appl. 4:1600382. doi: 10.1002/advs.201600382, Yang, H.-X., Zhao, D.-L., Lin, H., Tian, X.-M., Han, X.-Y., Duan, Y.-J., et al. The sodium or potassium, but not barium ferrate (VI), [FeO4]2, is soluble in water27. At a low potential, Fe ions are reduced on the surface of the electrode, and thus, are significantly adsorbed on the electrode. The 150th CV is shown in red. Res. Considering that different applications have special requirements for capacity and potential, two AFSCs are assembled in both parallel (Figure 6A) and series connections (Figure 6B). Rttinger, W. & Dismukes, G. C. Synthetic water-oxidation catalysts for artificial photosynthetic water oxidation. Kamber, D. N. et al. Nano Energy 11, 211218. Both oxidation and reduction peaks for Ni in the presence and absence of Fe changed linearly by (scan rate)1/2. Of particular importance is that -Ni(OH)2 electrode also possesses excellent rate capability, remaining a superior capacitance value of 60% (869 F g1) at a scan rate of 20 mV s1, which attributes to the unique ultra-thin structure. Soc. Mater. For GO, there was a characteristic diffraction peak at 2 = 12.5, indicating the successful oxidation of the spectral pure . From the inset of Figure 2C, it can be seen that the nanoplates are extremely thin. Electrochemical reactions at both positive and negative electrodes in a nickel metal hydride (Ni-MH) battery during charge have been investigated by in situ neutron powder diffraction. doi: 10.1039/C9NR08722B, Zha, D.-S., Sun, H.-H., Fu, Y.-S., Ouyang, X.-P., and Wang, X. Funct. M.M.N. The key to writing proper ionic formulas is simple: the total positive charge must balance the total negative charge. Figure 3F shows the cycling stability of -Ni(OH)2 electrode after charging-discharging 5,000 times at 3 A g1. (2013). Mohammad Mahdi Najafpour. The peak of Ni 2p3/2 is located at 855.6 eV with a shake-up satellite (denoted as Sat.) peak at about 861.5 eV; meanwhile, Ni 2p1/2 characteristic peak is located at 873.2 eV with a shake-up satellite peak at about 879.9 eV. Chem. Angew. This phenomenon maybe due to the diffusion movement of electrolyte ions is limited during high charging-discharging process. PDF Ion Exchange for Dummies - Lenntech The subtraction of orange plot in (b) of green plot in c (d). (D) GCD curves at different current densities. (2015). 49, 49564966. Front. 1, 814815, https://doi.org/10.1038/s41929-018-0179-1 (2018). J. S9). Chem. However, the negative electrodes use a hydrogen-absorbing alloy instead of cadmium. Soc. Google Scholar. Roy, C. et al. Funct. The heavy metal contaminated wastewater finds its way into the environment, threatening human health and the ecosystem. As shown in Fig. Structureactivity correlations in a nickelborate oxygen evolution catalyst. Rev. Design of FeCo2S4@Ni(OH)2 core-shell hollow nanotube arrays on carbon paper for ultra-high capacitance in supercapacitors. 3c, at 1.46V in KOH (pH13), adding the Fe salt in the first step had a significant effect. The Supplementary Material for this article can be found online at: https://www.frontiersin.org/articles/10.3389/fchem.2020.602322/full#supplementary-material, Cai, F.-S., Zhang, G.-Y., Chen, J., Guo, X.-L., Liu, H.-K., and Dou, S.-X. (B,C) The SEM images at different magnifications. Chem. In contrast to Fe(III), [FeO4]2 has a negative charge, and its migration toward the anode is easier than the migration of Fe(OH2)63+ with the positive charge. Ed. S3 and S4). 1a, in the absence of the [FeO4]2- and the presence of the impurity of Fe impurity in KOH or electrochemical cell, an increase in OER (orange arrow) is observed during the consecutive CVs. Chem. Chem. Novel coreshell FeOF/Ni(OH)2 hierarchical nanostructure for all-solid-state flexible supercapacitors with enhanced performance. The demonstrated performance for AFSCs suggests a great potential to convert and store energy for portable and wearable electronic devices. SEM images of the anodic Ni foam in the presence of the Fe salt with different magnifications (fh). Commun. Enhanced cycling stability of hierarchical NiCo2S4@Ni(OH)2@Ppy core-cell nanotube arrays for aqueous asymmetric supercapacitors. Biomass-derived C/N co-doped Ni(OH)2/NixSy with sandwich structure for supercapacitors. Nickel hydroxide | H2NiO2 | CID 61534 - PubChem One material, multiple functions: graphene/Ni(OH)2 thin films applied Results of the calculations in Example 17.4 have just shown the spontaneous process is described by a positive cell potential while the nonspontaneous process exhibits a negative cell potential. If material is not included in the articles Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. If OER of K2FeO4 is affected by the Ni(II) salt or not? A positive reduction potential indicates a spontaneous reaction. doi: 10.1021/acsami.5b07528, Zhang, Y., Yu, L., Hu, R., Zhang, J.-L., Niu, R.-C., Qian, X.-Y., et al. The specific capacitance and rate capability at different scan rates are shown in Supplementary Figure 3. Adv. Before adding the Fe salt at (0.141.86V) range (Fig. Am. Amperometry at 1.46V in KOH (pH13) in a two-compartment electrochemical cell for 2hours. SWV of Ni foil after the 100 CVs (green) (d). Practice Problem 1: Determine which element is oxidized and which is reduced when lithium reacts with nitrogen to form lithium nitride. Flexibility is also an importance index for practical application. Finally, oxygen-evolution measurements of K2FeO4 and Ni2O3 are investigated under chemical conditions. 2018A610183). Sci. Layered Ni(OH)2-Co(OH)2 films prepared by electrodeposition as charge ACS Nano 7, 62376243. After 80 consecutive CVs, a constant current was observed for OER (Fig. In the presence of the Fe salt (0.25mM), the subtraction shows that the Fe salt decreases the capacitance of Ni oxide at 1.361.46V range (A area). Chem. FeNi intermetallic compound nanoparticles wrapped by N-doped graphitized carbon: A novel cocatalyst for boosting photocatalytic hydrogen evolution. A gas is produced at the negative electrode. Wang, Q. One limitation of water-splitting reaction is OER3. Surf. Please enable JavaScript
115, 1297413005, https://doi.org/10.1021/acs.chemrev.5b00122 (2015). Using 18O-labeling experiments in combination with in situ Raman spectroscopy, it was found that lattice oxygen is involved in OER by Ni and Ni/Co LDHs, but not when Ni-Fe and Ni/Co/Fe LDHs are involved23. Other elements do not considerably affect OER of Ni oxide. In 2018, Chorkendorffs group electrochemically oxidized the nanoparticles of metallic Ni-Fe alloy in an electrolyte containing H216O to form NiFe16OxHy; in the next step, they added H218O to the electrolyte. In the meantime, to ensure continued support, we are displaying the site without styles Only a trace amount of Fe could significantly activate Ni oxide for OER (Fig. 5c). The previous section described the spontaneous oxidation of copper by aqueous silver(I) ions, but no observed reaction with aqueous lead(II) ions. The electrochemical performance of the asymmetric AFSCs was also studied by the same testing devices. Boettcher, S. W. Oxygen stays put during water oxidation. Ni(OH)2 nanoplates grown on graphene as advanced electrochemical pseudocapacitor materials. [6], Nickel(II) hydroxide has two well-characterized polymorphs, and . Figures 2E,F shows the XPS curves of Ni and O elements in Ni(OH)2 nanoplate. The -Ni(OH)2 electrode obtained has a high specific surface area of 164 m2 g1 and a significantly enhanced specific capacitance (2814 F g1 at 3 A g1), both higher than previously reported -Ni(OH)2. According to the GCD curves, the specific capacitance (F g1) of the AFSC can be calculated by Equation 6 (Wu et al., 2017): Where I (A) is the discharge current, m (g) is the mass of the active material, t (s) is the discharge time, and V (V) is the potential window. 134, 68016809, https://doi.org/10.1021/ja301018q (2012). Copper is a chemical element with the symbol Cu and atomic number 29. Article In the low frequency region, the Nyquist plot is almost a vertical line, while the shape of bare Ni foam is like an semi-circle, suggesting the -Ni(OH)2 nanoplates have good capacitive behavior. Oxygen-evolution reaction by nickel/nickel oxide interface in the To further evaluate the application potential of -Ni(OH)2 electrode for energy storage, a rechargeable asymmetric AFSC configuration is built based on AC negative electrode and -Ni(OH)2 positive electrode, as schematically illustrated in Figure 4A. Am. Nickel Cadmium Battery - an overview | ScienceDirect Topics Electrochemical Reactions - Division of Chemical Education, Purdue To further study the capacitive behavior, the Nyquist plot is presented in Figure 4E. 1a). 7, 22032212, https://doi.org/10.1039/C4EE00681J (2014). Interestingly, immediately after the interaction of the Fe salt with the electrode, a significant increase in OER was observed (see the video, SI). Iron oxide deposited on metallic nickel for water oxidation. Behavior in Fire: Converts to black nickelic oxide (Ni 2 O 3 ). 10nm) were observed on the surface of the cellular structure of the foam (Figs. Figure 5. 8). According to the CV curves, the specific capacitance (F g1) of the -Ni(OH)2 electrode can be calculated through following equation (Wu et al., 2017): Where I (A) is the instantaneous current in CV curve, m (g) is the mass of the active material, v (mV s1) is the scan rate which represents the speed of the potential change during the positive and negative sweeps in the CV measurement, and V (V) is the applied potential window which presents the range of potential change. The results show that the composite electrode material . The structure consists of Ni(OH)2 layers with intercalated anions or water. All anions are replaced by hydroxide (OH-) ions. The raw data supporting the conclusions of this article will be made available by the authors, without undue reservation. Thus, it is hypothesized that Fe sites could be active sites for OER. (2017). It was demonstrated that Ni(III) in the -NiOOH-like phase has no activity. 20 Articles, This article is part of the Research Topic, https://doi.org/10.3389/fchem.2020.602322, https://www.frontiersin.org/articles/10.3389/fchem.2020.602322/full#supplementary-material, Creative Commons Attribution License (CC BY). Corrigan (1987) studied the effects of Fe (0.01% Fe present) on OER by Ni oxide11. Solubility and Complex-Ion Equilibria - Division of Chemical Education Ni(II)/(III) oxidation is also revealed at 1.43V (Eq. Soc. The oxidation peaks shifted to higher potentials, and reduction peaks shifted to lower potential in the presence of Fe ions. Example 1. In addition to the electrochemical experiments, OER by [FeO4]2 and Ni2O3 was also investigated, and the results are reported. Chem. To obtain J. C+ (F g1) and C (F g1) stand for the specific capacitance of positive and negative electrode, respectively. The findings suggested that the incorporation of Fe ions in Ni oxide causes the Tafel slopes to drop from about 70mV/decade to about 25mV/decade11. School of Chemistry and EaStCHEM, University of Edinburgh, King's Buildings, David Brewster Road, Edinburgh, Scotland EH9 3FJ, UK
11029 R Plz, Omaha, Ne 68137,
Your Application Has Been Dispatched To The Ircc Office,
Potato Reese's Nutrition,
Best Hotels In Baja California Sur,
Articles N
